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Phytochemicals are secondary plant metabolites that are present usually in small and varying quantities and that have speci c functions in the plants natural development, growth, and resistance to pathogens and predators A plethora of different chemicals and structures have been de ned in the past century in food plants, and it would be out of the scope of this chapter to elaborate in any great detail on these In particular the dietary phytochemicals have attracted much attention as to their chemoprotective properties, with mounting evidence indicating protection against several chronic disease states such as diabetes type 2, certain cancers, and CVD In this section, phytochemicals originating from unprocessed and processed cocoa, tea, coffee, and whole grain will be discussed 9221 Cocoa Cocoa and cocoa-related products have in recent years attained widespread recognition as an important source of dietary polyphenols.

Cocoa is manufactured from cocoa beans, which are in essence the seeds of the cocoa tree Theobroma cacao Whereas coffee and tea are extracts of plant parts, cocoa is eaten as a whole Cocoa is in fact the nonfat component of cocoa liquor (the nely ground cocoa beans), which is used in chocolate making, or as cocoa powder, commonly with 12% fat and used in beverages such as chocolate drinks and in the confectionery and baking industries The chemical constituents of cocoa have been subject of intense study in the past two decades, and focus has been on the polyphenolic fraction that comprises about 62% of the cocoa nib (the dried and roasted kernel of the cocoa bean that remains after the cocoa bean husk has been removed) (40) The most important subclass of particular interest to the scienti c community is the avanols (also termed avan-3-ols or catechins).

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The main catechins in cocoa are ( )-epicatechin and (+)-catechin, as well as catechin dimers or oligomers/polymers made of up to 10 units and commonly referred to as procyanidins (Fig 95) (41) 92211 Chemical Changes during Processing The production of the different cocoa fractions encompasses several steps The chocolate and cocoa industry use a large assortment of different equipment, techniques, and condi-.

R1 = H, R2 = OH = (+)-Catechin (2R, 3S) R1 = OH, R2 = H = (-)-Epicatechin (2R, 3R)

Decoding Sequential-Mode JPEG Images marker is read ReadMarker determines the marker type and then calls functions that decode specific markers ReadQuantization The ReadQuantization function processes a DQT marker The JpegDecoderQuantizationTable objects read the actual quantization tables from the input stream A DQT marker may define multiple quantization tables, so this function determines how many tables the marker contains and the identity of each one ReadHuffmanTable This function is very similar to ReadQuantization except that it reads DHT markers The actual Huffman table data is read by the JpegHuffmanDecoder objects This function reads Huffman tables until no more remain in the marker data ReadStartOfFrame The ReadStartOfFrame function reads SOFn markers All SOFn markers have the same format, so the same function is used to read all types The decoder relies upon the ReadMarker function to determine if the SOFn marker is one supported by the decoder ReadStartOfScan The ReadStartOfScan reads an SOS marker from the input stream It determines the components that make up the scan and then stores a list of pointers to the corresponding JpegDecoderComponent objects within the scan_components array ReadSequentialInterleavedScan and ReadSequentialNonInterleavedScan The ReadSequentialInterleavedScan and ReadSequentialNonlnterleavedScan functions control the reading of data units from the input stream The former is used when the current scan contains more than one component; the latter is used when there is only one component in the scan The individual component objects read the DCT coefficients into the data units However, this function determines the ordering of the components and which data unit is read for each component They also keep track of the number of data units read and compare this to the restart interval in order to determine when a restart marker must be read

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tions of processing, and it is out of the scope of this chapter to elaborate on any of the unit operations Typically, it begins with the slicing of the cocoa pods (the fruit), and withdrawal of the pulp and beans, the latter subsequently fermented, which can take 3 7 days After fermentation, the seeds are usually sun-dried for about 6 days, down to a moisture content of below 8% The beans during this stage turn darker color due to the oxidation of phenolic compounds In brief, the next steps of cocoa processing are more complex and comprise a roasting step typically at temperatures ranging from 110 to 140 C for 20 to 40 min (42) This is the most important step for avor development (43).

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